Geochemical Characteristics of Clay Deposits, Bussaya Area, Southern Iraq
DOI:
https://doi.org/10.24237/ASJ.02.04.785CAbstract
This study concerned with the geochemical characteristics of clay deposits belong to Nfayil
beds (Middle Miocene) in Al Muthana Governorate southern Iraq, as a new resource of clay
raw material. Twenty three samples of clay deposits were analyzed by using X-Ray
Fluorescence technique (XRF) for the major oxides; (SiO2, Al2O3, Fe2O3, MgO, CaO, Na2O,
K2O, TiO2, and L.O.I), and trace elements; (V, Cr, Co, Ni, Cu, Zn, As, Sr, Pb, Ga, Rb, Ba, and
Zr). The chemical results demonstrated due to the relation between Sr and Cu, that the
depositional environment predominated by hot and arid paleoclimate conditions, while from the
relation between Al2O3 with (Al2O3, CaO, Na2O, and K2O) reveals a low to relatively moderate
chemical weathering. Whereas the ratio of Ni/Co reveals that the deposition was within hypoxic
environment, while due to the ratio of Al2O3 / TiO2 in which advocated by Ti- Zr relation which
demonstrates that the intermediate igneous rocks as a provenance of the studied clays.
References
W. W. Olive, A. F. Chleborad, C. W. Frahme, Shlocker, Julius, R. R. Schneider, R. L. Schuster, Swelling Clays Map of the Conterminous United States, (1989)
V. K. Sissakian, A. I. Mahdi, R. M. Amin, B. M. Salman: The Nfayil Formation: A new litho-stratigraphic unit in the Western Desert of Iraq, Iraqi Geological Journal, 30(1), 61–65 (1997)
M. T. Zaini, W. P. Beshir, K. N. AL-Kubaisi, F. Z. Kadhem, B. A. AL-Samarraie, H. A. Mousa, A. Al-Obaidy, Report on geological mapping scale 1:25 000 of south AL-NASIRIYA area (second stage). GEOSURV, int. rep. no. 3523 (2014)
S. T. Ahmed, H. Dh. Abdulwhab, M. F. Karim, Investigation of stratigraphic clay and sand in Al Muthana Governorate, category C2, Iraq Geosurv, Internal report (2022)
C. Micó, L. Recatalá, M. Peris, J. Sánchez, Assessing heavy metal sources in agricultural soils of an European Mediterranean area by multivariate analysis, Chemosphere, 65(5), 863-872 (2006)
F. H. Tobia, S. S. Shangola, Geochemistry of sandstones from Beduh formation in northern thrust zone, Kurdistan region, northern Iraq: provenance and tectonic sett, The Iraqi Geological Journal, 15-39 (2019)
N. S. Heier, G. K. Billings, Lithium. In: Wedepohl, K.H. (Ed.), Handbook of Geochemistry, Springer, Berlin, 3- G–13-H-1 (1978).
M. A. Al-Jobouri, Geochemistry of Colored Argillites of Fat'ha Formation (Middle Miocene) and their Industrial Significance at Selected Areas in Northern Iraq, M.Sc. thesis, College of Science, Mosul University, (in Arabic) (2005)
S. Landergren Vanadium; In: Handbook of Geochemistry (ed.) Wedepohl K W, (Springer-Verlag, Berlin, 1978), 23.D.1–23.D.10 1978
Y. M. Zainal, Mineralogy, Geochemistry and Origin of some Tertiary bentonite in Iraq. Ph.D. thesis, Sheffield, University of Sheffield. U.K. (1977)
S. Mackenzie, R. L. Patience, J. R. Maxwell, M. Vandenbroucke, and B. Durand, Molecular parameters of maturation in the Toarcian shales, Paris Basin, France. Changes in the configurations of acyclic isoprenoid alkanes, steranes and triterpanes. Geochimica et Cosmochimica Acta, 44(11), 1709-1721 (1980)
H. Farrah, W. F. Pickering, Extraction of heavy metals ions sorbed on clays, Water, Air and Soil Pollution, 9, 491-498 (1977)
E. Callender, Heavy metals in the environment-historical trends. Treatise on Geochemistry, 9, 67–105 (2003)
D. O’Connor, D. Houm, Y. J. Zhang, Y. S. Song, L. Tian, Lead-based paint remains a major public health concern: A critical review of global production, trade, use, exposure, health risk, and implications, Environmental International, 121, (2018)
P. Madejon, (2012). Barium. In: Alloway, B.J. (Ed.), Heavy Metals in Soils. Trace Metals and Metalloids in Soils and Their Bioavailability, Springer Science + Business Media, the Netherlands, Dordrecht, 507- 514 (2012)
V. M. Goldshmidt, Geochemistry, Oxford university press, London, 730p (1970)
K.K. Turekian, Wedepohl, K. H.: Distrybution of the elements in some major units of the Earth’s crust, (Geological Society of America, bulletin 72, 1961), 175-192
J. S. Tooms, C. P. Summerhayes, D. S. Cronan, , Geochemistry of marine phosphate and manganese deposits, Ann. Rev. Oceanog. Mar. Biol, 7, 247-266 (1969)
J. Madhavaraju, S. Ramasamy, Petrography and geochemistry of Late Maastrichtian-Early Paleocene sediments of Tiruchirapalli Cretaceous, Tamil Nadu – Paleoweathering and provenance implications. – J. Geol. Soc. India. 59: 133 –142 (2002)
P. O. D. Andersson, R. H. Worden, D. M. Hodgson, S. Flint, Provenance evolution and chemostratigraphy of a Palaeozoic submarine fan-complex: Tanqua Karoo Basin, South Africa. – Mar. Petrol. Geol. 21, 555 – 577 (2004)
K. Hayashi, H. Fujisawa, H. Holland, H. Ohmoto, Geochemistry of 1.9 Ga sedimentary rocks from northeastern Labrador, Canada. Geochim. Cosmochim. Acta., 61, 4115 – 4137 (1997)
H. W. Nesbitt, G. M. Young, Early Proterozoic climates and plate motions inferred from major element chemistry of lutites, Nature Journal, 299, 715-717 (1982)
C. Baiyegunhi, K. Liu, O. Gwavava Geochemistry of sandstones and shales from the Ecca Group, Karoo Super group, in the Eastern Cape Province of South Africa: Implications for provenance, weathering, and tectonic setting. Open Geosciences, 9, (1), 340-360 (2017)
M. Honda, H. Shimizu, Geochemical, mineralogical and sediment-logical studies on the Taklimakan Desert sands. Sedimentology, 45, (6), 1125-1143 (1998)
M. Singh, M. Sharma, H. J. Tobschall, Weathering of the Ganga alluvial plain, northern India: implications from fluvial geochemistry of Gomati River, Applied Geochemistry, 20, 1-21 (2005)
R. A. Obasi, H. Y. Madukwe, Use of geochemistry to study the provenance, tectonic setting, source-area weathering and maturity of Igarra marble, Southwest, Nigeria. American Journal of Engineering Research, 5, (6), 90-99 (2016)
M. A. Ramos-Vázquez, J. S. Armstrong-Altrin, L. Rosales-Hoz, M. L. Machain-Castillo, and A. Carranza-Edwards. Geochemistry of deep-sea sediments in two cores retrieved at the mouth of the Coatzacoalcos River delta, western Gulf of Mexico, Mexico. Arabian Journal of Geosciences, 10(6), 1-19(2017)
Anaya-Gregorio, Abigail, Textural and geochemical characteristics of late Pleistocene to Holocene fine-grained deep-sea sediment cores (GM6 and GM7), recovered from southwestern Gulf of Mexico, Journal of Palaeogeography, 7.1, 1-19(2018)
S. Faraj, S. Pachidi, and K. Sayegh. Working and organizing in the age of the learning algorithm. Information and Organization, 28(1), 62-70 (2018)
D. M. McKirdy, P. A. Hall, Paleoredox status and thermal alteration of the lower Cambrian (series 2) Emu Bay shale Lagerstatte, South Australia. Australian J Earth Sci, 58: p 259 – 272 (2011)
B. M. S. Yandoka, H. A. Wan, M. B. Abubakar, M. H. Hakimi, A. K. Adegoke, Geochemical characterization of Early Cretaceous lacustrine sediments of Bima Formation, Yola Sub-basin, Northern Benue Trough, NE Nigeria: Organic matter input, preservation, paleoenvironment and palaeoclimatic conditions, Mar. Petrol. Geol. p 61, 82. (2015)
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